Fillers for Wear-Resistant Matte Coatings

Fillers for Wear-Resistant Matte Coatings
I. Hard Abrasive-Type Fillers (Provide both wear resistance and a matte finish; suitable for UV-curable coatings, powder coatings, and wear-resistant anti-corrosion paints)
1. White Fused Alumina (WA) Micropowder

White aluminum oxide
White fused alumina WFA

With a Mohs hardness of 9, White Fused Alumina (WA) is white, highly bright, and low in iron content. Its angular particles serve a dual purpose: they create a wear-resistant structural framework while simultaneously scattering light from their surfaces to produce a matte or frosted effect.
Suitable for: Transparent UV-curable coatings, light-colored/white ceramic-modified fluorocarbon powder coatings, and non-stick coatings for cookware.
Drawbacks: The particles have sharp edges; if the fine powder is not dispersed properly, it may cause micro-scratches. Not suitable for pure black systems.
2. Green Silicon Carbide (GC) Micropowder

Green Carborundum GC
Green Silicon Carbide GC

Green Silicon Carbide (GC) has a Mohs hardness of 9.4, offering superior wear resistance and good thermal conductivity.
Suitable for: Black or dark-colored wear-resistant anti-corrosion coatings, anti-static wear-resistant paints, and thermal control coatings for aerospace applications.
Drawbacks: Cannot be used in light-colored or transparent clear coats, as it will cause discoloration.
3. Black Silicon Carbide (SiC) Micropowder

Black carborundum
Black Silicon Carbide SiC

Black Silicon Carbide (SiC) has a Mohs hardness of 9.15. It is black in color and offers a higher cost-performance ratio.
Suitable for: Wear-resistant floor coatings, thermal insulation and fire-retardant composite coatings for lithium-ion batteries, and general dark-colored wear-resistant anti-corrosion paints.
Drawbacks: Not for use in light-colored systems. Due to its high free-carbon content, it should be used with caution in applications requiring high electrical insulation.
4. Brown Fused Alumina (BFA) Micropowder

Brown aluminum oxide
Brown Fused Alumina BFA

Brown Fused Alumina (BFA) has a Mohs hardness of 9. It is brownish in color, contains iron, and is the most economical option.
Suitable for: Heavy-duty epoxy flooring and dark-colored primers for construction machinery.
Drawbacks: Not suitable for light-colored coatings, coatings applied to aluminum or titanium substrates, or products requiring high weather resistance, as it is prone to causing rust spots or yellowing.

II. Other Inorganic Wear-Resistant Matte Fillers
1. Fused Silica Powder / Crystalline Silica Powder (SiO₂)
With a Mohs hardness of 7 and a refractive index close to that of resins, it ensures good transparency in clear coats. It provides a soft matte finish, moderate wear resistance, and excellent electrical insulation. It is used in electronic insulating coatings, UV-curable wood coatings, and transparent matte topcoats. However, its wear resistance is lower than that of white fused alumina or silicon carbide, making it unsuitable for heavy-duty, high-erosion environments.
2. Calcined Alumina (Non-fused; distinct from white fused alumina)
Typically spherical or near-spherical in shape, it is finer than white fused alumina, posing a lower risk of scratching. It offers a soft matte finish and is frequently used in high-end optical coatings.
3. Platelet white aluminum oxide

Platelet aluminum oxide
Platelet White Aluminum Oxide
Platelet aluminum oxide SEM picture
Platelet aluminum oxide SEM picture

Characterized by a plate-like or flaky structure, this material provides wear resistance, UV protection, and resistance to moisture vapor permeability. It yields a smooth, fine matte finish and is commonly used in automotive paints and baked metal coatings.
4. Barium Sulfate, Kaolin, and Diatomaceous Earth
These are lower-cost matte fillers with significantly weaker wear resistance. Their primary function is to provide a matte effect; any wear resistance they offer is merely incidental rather than a core functional property.
5. Fumed Silica (Pyrogenic Silica)
A nanoscale material primarily used for matting, anti-settling, and thixotropic control. It offers only limited improvement to wear resistance and is typically used in combination with hard abrasive fillers rather than serving as a wear-resistant filler on its own.

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